Friday, 3 July 2020

Dead alkaline batteries


What is this? A small collection of dead alkaline batteries.

Collection of dead alkaline batteries

Although presented to me as dead they weren't all in that state, as their measured outputs ranged from 0.05 to 1.55 V (after I looked at them again I noticed that one was a rechargeable, doh!).

Measuring voltage of unloaded batteries

The C and AAAA cells can be put back to general use as OK(ish). The rest would usually be put out for recycling but I got to thinking… is there another use for them?

So, what is an alkaline battery made from?

Diagram of the internal parts of an alkaline battery

A variety of things it appears. The chemicals inside are Zn/ZnO and Mn(III) and Mn(IV) species plus some KOH wrapped up in a stainless steel can with a brass current collector. Nothing I really need to play around with at the moment, and it's not like dead batteries are hard to come by. So that's a pass on the raw materials.

When I measured the voltage of the remaining 3 AA cells they were 0.05, 0.55 and 1.12 V, indicating that they are all pretty dead, ie there was not even any juice to be recovered by using them in a less demanding item. It is possible to charge alkaline cells another couple of times with a special charger (such as this one), but generally they are pricey for what they are and are not recommended. Making one would be a nice scratch build, but that is a project for another day.

Chart to assess the remaining charge of an alkaline battery

So the answer to the question of 'is there anything else I can do with them?' is, not really. Off to the recycling bin it is then.

JOB DONE

Time taken: 5 mins
Cost: £0.00

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